@Article{VernasquiSISLSFR:2023:NeDiCo,
               author = "Vernasqui, Lais Gimenes and Santos, Gessica de Oliveira Santiago 
                         and Isidro, Julia and Silva, Taynara Oliveira and Lanza, Marcos 
                         Roberto de Vasconcelos and Saez, Cristina and Ferreira, 
                         Neiden{\^e}i Gomes and Rodrigo, Manuel Andres",
          affiliation = "{Instituto Nacional de Pesquisas Espaciais (INPE)} and 
                         {Electrochemical \& Environmental Engineering Lab} and 
                         {Electrochemical \& Environmental Engineering Lab} and 
                         {Universidade de S{\~a}o Paulo (USP)} and {Universidade de 
                         S{\~a}o Paulo (USP)} and {Electrochemical \& Environmental 
                         Engineering Lab} and {Instituto Nacional de Pesquisas Espaciais 
                         (INPE)} and {Electrochemical \& Environmental Engineering Lab}",
                title = "New diamond coatings for a safer electrolytic disinfection",
              journal = "Environmental Science and Pollution Research",
                 year = "2023",
               volume = "30",
                pages = "117871--117880",
             keywords = "Disinfection, Diamond electrodes, Chlorine, Perchlorate, E. coli, 
                         Reclaiming.",
             abstract = "In this work, a new coating of boron-doped diamond 
                         ultra-nanocrystalline (U-NBDD), tailored to prevent massive 
                         formation of perchlorates during disinfection, is evaluated as 
                         electrode for the reclaiming of treated secondary wastewater by 
                         the electrochemically assisted disinfection process. Results 
                         obtained are compared to those obtained by using a standard 
                         electrode (STD) that was evaluated as a standard in previous 
                         research showing outstanding performance for this application. 
                         First tests were carried out to evaluate the chlorine speciation 
                         obtained after the electrolysis of synthetic chloride solutions at 
                         two different ranges of current densities. Concentrations of 
                         hypochlorite obtained using the U-NBDD anode at 25 mA cm\−2 
                         were 1.5-fold higher, outperforming STD anode; however, at 300 mA 
                         cm\−2, an overturn on the behavior of anodes occurs where 
                         the amount of hypochlorite produced on STD anode was 1.5-fold 
                         higher. Importantly, at low current density the formation of 
                         chlorates and perchlorates is null using U-NBDD. Then, the 
                         disinfection of the real effluent of the secondary clarifier of a 
                         municipal wastewater treatment facility is assessed, where 
                         inactivation of Escherichia coli is achieved at low charge applied 
                         per volume electrolyzed (0.08 A h L\−1) at 25 mA 
                         cm\−2 using the U-NBDD. These findings demonstrate the 
                         appropriateness of the strategy followed in this work to obtain 
                         safer electro-disinfection technologies for the reclaiming of 
                         treated wastewater.",
                  doi = "10.1007/s11356-023-30407-w",
                  url = "http://dx.doi.org/10.1007/s11356-023-30407-w",
                 issn = "0944-1344",
             language = "en",
           targetfile = "s11356-023-30407-w.pdf",
        urlaccessdate = "06 maio 2024"
}